Lipids are defined by their solubility in solvents like ether.
The most important lipids are fats and oils, which store energy;
these lipids are made from glycerol plus fatty acids.
IMPORTANT BUILDING BLOCKS:
Fatty acids: –COOH at the end of a long hydrocarbon chain.
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Saturated fatty acids contain single bonds only.
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Unsaturated fatty acids contain at least one double bond.
Other building blocks:
glycerol |
isoprene |
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FATS AND OILS:
- Monoglycerides and diglycerides: glycerol + 1 or 2 fatty acids.
- Triglycerides or fats: glycerol + 3 fatty acids
- Those liquid at room temperature are commonly called oils.
- For each fatty acid added to glycerol, one molecule of water splits out (dehydration).
- Fat digestion adds water molecules to split fatty acids from glucose.
- Fats have more calories per gram than most other compounds.
OTHER LIPIDS:
- Phospholipids (like phosphatidyl choline): occur mostly in membranes.
- Sphingolipids (like spingomyelin): have sphingosine instead of glycerol.
- Glycolipids (like cerebrosides and gangliosides in the brain):
have sugar instead of glycerol.
- Waxes are long-chain alcohols found in plants.
- Terpenes are odorous hydrocarbons in plants, composed of isoprene units.
- Carotenoids (carotenes and xanthophylls) are plant pigments composed of isoprene units.
- Steroids include cholesterol and its derivatives.
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