The older White Mountain igneous province is dominated by silica-oversaturated subaluminous to peralkaline rocks of associafion 1, including the White Mountain batholith. Two minor nepheline-bearing intrusions occur at Red Hill, New Hampshire, and Rattle snake Mountain, Maine. These two occurrences together with nepheline-bearing intrusions of the younger White Mountain province define a narrow zone that strikes at high angle to the NNE trend of the overall province (Figure 1; Creasy, 1989). To the nort h of this zone are found the large composite plutons and batholith of the older province; to the south only a few small scattered plutons of this age are present. In contrast, nearly all plutons of the younger White Mountain province are found to the sou th of this zone.
The Monteregian Hills and younger White Mountain igneous provinces represent the last period of igneous acfivity in New England (130-100 Ma). The bulk of the magmatism occurred ca. 125 Ma, but younger ages have been obtained for Little Rattlesnake (114 Ma, Foland and Faul, 1977) and Cuttingsville (100 Ma, Armstrong and Stump, 1971). Plutons emplaced to the west of Logan's line consist largely of mafic alkaline suites, many of which are nepheline norrnative. To the east of Logan's line, felsic ro cks are much more important components of the intrusions and silica-undersaturated rocks are not found. Some of these younger plutons show ring-like structures (Ossipee and Pawtuckaway) while others appear to he small plugs (e.g. Little Rattlesnake, Ascu tney, and Tripyramid). In most cases the most evolved rocks are syenites and quartz syenites, but biofite granites are found at Ossipee and Merrymeeting Lake.
This field excursion illustrates the White Mountain batholith [associations 1 and 2 ahove] which comprises about 50% of the total areal extent of the older White Mountain igneous province. The material in this field guide previously appeared in Creasy and Eby (1993).
INTRODUCTION
The geology of the White Mountain batholith is described by Billings (1928), Billings and Williams (1935), Creasy (1974), Davie (1975), Eby and others (1992), Fitzgerald (1986), Henderson and others (1977), Moke (1946), Osberg and others (1978), Parnell ( 1975), Smith and others (1939), Wilson (1969) and, Wood (1975). Granites, quartz syenites, and syenites account for about 97% of the 1,000 km2 area of the batholith; volcanic rocks of similar composition account for the remainder. Pink, medium-grained s ubalkaline biotite granite (the Conway Granite) and a green, medium-grained subalkaline to peralkaline amphibole granite (the Mount Osceola Granite) comprise 80% of the batholith. Medium-grained sub-alkaline to peralkaline amphibole syenites and quartz s yenites are widely distributed and are similar in occurrence, texture, and mineralogy to the Mt. Osceola. Distinctive porphyritic quartz syenite occurs in ring dikes in the western (the Mount Garfield) and the eastern (the Albany) halves of the batholith . Fine-grained syenite occurs in isolated outcrops spatially associated with the ring dikes.

Gabbro, diorite, and monzonite are present in the Mt. Tripyramid complex (Figure 2), a member of the younger White Mountain igneous province, that is spatially associated with the White Mountain batholith.

The eastern portion of the White Mountain batholith, exposed in the North Conway and Crawford Notch 15' quadrangles, has at least four magmatic centers (Figure 3). Two centers with thick pyroclastic successions are interpreted as calderas (Noble and Bil lings, 1967; Fitzgerald, 1987; Fitzgerald and Creasy, 1988). Other centers where ring dikes or crescent- shaped intrusions are associated with epizonal plutons define more deeply eroded calderas. Caldera development here post-dates similar events in the western batholith by about 10-20 Ma. Dated units include the ring dike of center E2 (179 Ma); the Moat Mtn volcanic sequence (173-168 Ma) and ring dike (170 Ma) of center E3; and plutons of biotite granite (171 Ma and 155 Ma). We interpret the White Mo untain batholith as a sub-horizontal slice through a caldera field cut about 1.5 km thick and 1-2 km below the original landsurface. This excursion illustrates the field characteristics and structural relations of plutons, ring dikes, and volcanics that constitute the eastern half of the White Mountain batholith (Figure 3).
The Mt. Osceola Granite is a medium- to coarse-grained hypersolvus granite that is dark green where fresh. It consists of an interlocking network of anhedral to subbedral microperthite 3-10 mm in diameter enclosing rounded grains of smokey quartz. Ferro hastingsite and locally annite are interstitial, late crystallized minerals. Fayalite (Fa95-99, Creasy, 1974) and sodic ferrohedenbergite (typical analysis Na3Ca40Fe56Mg1) are frequently present in accessory amounts and encased by reaction rims of ferroh astingsite. Characteristic accessories include allanite, sphene, zircon, fluorite, ilmenite, and monazite. Locally the Mt. Osceola is weakly peralkaline with ferrorichterite or riebeckite rimming ferrohastingsite. Miarolitic cavities may be locally abu ndant (one percent of outcrop area) and large (six to eight square centimeters). Pegmatite pods five to twenty centimeters across are abundant in many exposures of the Mt. Osceola Granite, locally forming up to two to three percent of the outcrop. Aplit e dikes, quartz veins, and fractures are abundant in all large exposures of the Mt. Osceola Granite. The aplitic dikes rarely exceed ten centimeters in width although they may be traced continuously for a hundred meters. Veins of quartz range from two t o five centimeters in width and commonly have open cores into which project well-formed crystals of quartz.

Peralkaline Granite. Riebeckite-arfvedsonite granite forms an arcuate dike and small pluton intruding the Conway Granite of the Green Hills pluton. Petalkaline granites also form larger areas of outcrop in the eastern (e.g. on North Doublehead, Parnell, 1975) and central (e.g. Hart Ledge area, Henderson and others, 1977) batholith that appear to be young plutons spatially and genetically associated with Mt. Osceola Granite. Contacts between the peralkatine granites and the Mount Osceola are commonly gr adational.
The peralkaline granites are composed of subhedral grains of white microperthite (5-10 mm) and clear quartz (2-6 mm), blocky interstitial grains of riebeckite-arfvedsonite (<10 mm), and flakes and aggregates of interstitial biotite. Characteristic of this rock are abundant radiating arrays of golden colored astrophyllite. Fluorite, ilmenite, sphene, and apatite are common accessory minerals. Near contacts, miarolitic pods and cavities are developed on a cm-scale; here prismatic riebeckite crystals a re found up to 5 cm in length. One small body within the Hart Ledge complex (Wood, 1975) contains ferrorichterite (7%) in place of riebeckite-arfvedsonite; fayalite and ferrohedenbergite are accessories.
Alkali feldspar Quartz Syenite. Quartz syenite forms a small pluton within magmatic center E1 (Figure 2) and two arcuate bodies associated with the Hart Ledge complex of the central batholith (Figure 2; Henderson and others, 1977). The Hart Ledge complex is the youngest igneous activity in the central portion of the batholith, 169-162 Ma (Eby and others, 1992).
The quartz syenite is composed of tabular subhedral crystals of microperthite (14 mm) Anhedral quartz (<2 mm) is interstitial to and never included within these crystals of microperthite. Rounded grains of sodic ferrohedenbergite averaging 0.5 mm are present in all specimens though in variable amounts; commonly, these grains are enclosed within the microperthite. Ferrorichterite, the most abundant mafic mineral, forms interstitial grains and reaction rims on sodic ferrohedenbergite. That a vapor pha se may have formed is suggested by the occurrence of riebeckite. Rieheckite forms very thin rims on ferrorichterite, coats fractures within the ferrorichterite and penetrates pyroxene within. Further, tufts of acicular needles of riebeckite grown on a s ubstrate of ferrorichterite project into grains of quartz. These needles commonly less than one micron in diameter seems to dictate growth from a vapor phase. Ilmenite, allanite, zircon, and sphene are common accessories.
Alkali-feldspar Syenite. Syenite is an uncommon plutonic member of the White Mountain magma series; only two are described from the White Mountain batholith. The syenite occurring in the central portion of the batholith (Figure 2; W ood, 1977; Henderson and others, 1977)) ispart of the Hart Ledge complex. The syenite is a coarse rock, dark green where fresh; blocky microperthite and ferrohastingsite (about 10%) account for ninety-five percent of the hand specimen; fayalite and ferroh edenbergite are minor accessories. The syenite contains miarolitic pods of coarse prismatic ferrohastingsite and irregularly-shaped quartz.
The syenite is of interest because of the spatial and genetic relationship to the widespread Mt. Osceola Granite and to the peralkaline granites and quartz syenite. Significantly, REE data for the Hart Ledge complex (Creasy and others, 1979; Eby and othe rs, 1992) show a positive europium anomaly for the syenite, but substantial negative anomalies for the quartz syenites and peralkaline granites. The syenite may represent the cumulus feldspar and the peralkaline granites may represent residual liquids de rived from the crystallization of a Mount Osceola-type parental magma. No other analyzed rocks from the batholith show negative Europium anomalies.
The variation in composition of these amphiboles, consistent with principles of crystal fractionation, suggests the riebeckite granite is more strongly fractionated than the other two units. The Mt. Osceola Granite, the quartz syenite of Mt. Tremont, and the riebeckite granite, respectively, were derived from the same or similar magmas that had undergone increasingly greater degrees of CryStal fractionation. The apparent variation in degree of fractionation may reflect the sequential evolution of a sing le parent magma or may result from the exposure, at current levels of erosion, similar magmas that had fractionated to differing degrees.
The Conway Granite is a medium- to coarse-grained pink biotite two-feldspar granite. Values of microperthite:oligoclase range from 2:1 to 10:1 and average 4-5:1 (Creasy, 1974). Annite (Ann90) forms anhedral interstitial grains up to 5 mm in size. In co ntrast with other members of the White Mountain magma series, fayalite and ferrohedenbergite are absent. Subordinate amphibole is present in some samples. Zircon, allanite, apatite, sphene, and fluorite are common accessories. Near intrusive contacts, the Conway Granite shows a variety of textures that may grade into each other on the outcrop scale: porphyritic, aplitic, miarolitic, and pegmatitic. Miarolitic cavities are typically of mm-scale and bounded by euhedral crystals of quartz and feldspar. A zone of miarolitic cavities ranging up to several meters is present within the Conway Granite adjacent to the Moat volcanics on the east side of the Moat Range. This and similar occurrences of miarolitic cavities in the eastern batholith have produced many beautiful smokey quartz crystals. Weakly developed banding on the cm- to dm-scale resulting from variations in grain size and/or mineral concentrations is developed near some contacts. Lithic fragments of any type are sparse in the Conway Granite.< p> Black Cap Granite. The Black Cap Granite (Billings, 1928) is a fine-grained pink aplitic biotite granite that outcrops in two small areas in the North Conway quadrangle. It is composed of quartz, microperthite, subordinate oligiocla se, and chloritized biotite. Accessories include zircon, magnetite, apatite, and fluorite. The Black Cap Granite is shattered and intruded by the Conway Granite (Green Hills pluton) on the flanks of Black Cap. Billings considered this rock an early lit hologically distinct 'phase' of the Conway Granite. Osberg and others (1978) suggest that the Black Cap granite to be coeval with and a roof facies of the Conway Granite.
| Stop No. Quartz Alkali feldspar Plagioclase Biotite Amphibole Ferrohedenbergite Fayalite Accessories | #la 35 49 14 2 0 0 0 tr | #lb 22 72 3 tr 1 tr 2 tr | #2a 10 79 0 1 8 8 1 3 | #2b 16 70 0 0 9 2 tr 3 | #2c 20 68 0 tr 1 tr 3 |
| Stop No. Quartz Alkali feldspar Plagioclase Biotite Amphibole Ferrohedenbergite Fayalite Accessories | #5 13 74 0 1 12 0 0 tr | #6 29 48 17 6 0 0 0 tr | #7 33 49 16 2 0 0 0 tr | #8 39 54 0 1 5 0 0 1 | #9 28 47 18 7 0 0 0 1 |
| la lb 2a,b,c 5 6 7 8 9 | Conway Granite, Birch Hill pluton, Hurricane Mtn Road. Mt. Osceola Granite, Rattlesnake Mtn, Redstone area. Albany Porphyritic Quartz Syenite, three distinct types within ring dike E3, Little Attitash Mtn. Albany Porphyritic Quartz Syenite, Jackson Falls. Black Cap Granite, Thorn Mtn. Conway Granite, Gardiner Brook pluton, Burnt Knoll Brook. rieheckite granite, North Doublehead. Conway Granite. Green Hills pluton, Black Cap mountain. |
In fine structure individual ring dikes are themselves multiple intrusions. For example, at least four separate intrusions of porphyritic quartz syenite and syenite occur in ring E3 (Table 1; Figure 3). The increasing abundance of feldspar phenocrysts a nd of total quartz content with decreasing age suggests (Davie, 1975) successive differentiates of a subjacent magma body. Inclusions present in ring BI document a similar structural relationship.
The groundmass is uniform in grain size (<2-3 mm) within an intrusion (except near contacts) but shows variation among different intrusions. Minerals of the groundmass are anhedral quartz, alkali feldspar, subordinate oligioclase, and minor ferrohasti ng site and annite. Ferrohastingsite occurs as anhedral interstitial grains and as rims on the ferrohedenbergite and fayalite. In both occurrences it may poildiltically enclose small quartz grains. Grunerite is found as reaction rims on fayalite and is surrounded by ferrohastingsite. Accessories include allanite, sphene, zircon, and fluorite. Secondary sericite, biotite and chlorite are commonly present.
The mineralogic transition from the anhydrous phenocryst (intratelluric) assemblage to the hydrous groundmass (emplacement) assemblage is written as a simplified end-member reaction (Creasy, 1974):
Fe2SiO4 + 2CaFeSi2O6 + FeTiO3 + [NaA1Si3O8 + H20] --> NaCa2Fe(2+)Fe(3+)Si6(Al,Ti)2O22(OH)2 + [2SiO2]
fayalite + 2 ferrohedenbergite + ilmenite + albite = ftrrohastingsite + quartz,
where [ ] indicates probable melt components. The stabilization of the hydrous phase, ferrohastingsite, relative to layalite and ferrohedenbergite requires a reduction in temperature or a combined reduction in temperature and total wessure. The textural
and physicochemical changes coincide with emplacement of the ring dikes.

Keaasarge North (E4, Figure 3) exposes a mix of comendite, feldspathic tuff, and meso- and megabreccias (Billings, 1928) similar to those found on North Moat. The comendites lie topographically below the more extensive breccias and are lithic-rich. As i n the Moat Range sequence, the breccias on Kearsarge North are polymict (although in any horizon one or another clast lithology may predominate) and the matrix: clast ratio varies greatly.
The comendites are blue-gray to pink rocks contain variably abundant phenocrysts (1-3 mm) of quartz and microperthite and rare phenocrysts of biotite, ferrohastingsite, ferrohedenbergite, and riebeckite set in a matrix of quartz and alkali feldspar. Acce ssories include apatite, fluorite, zircon, and magnetite. Lithic fragments (mm- and cm-scale) constitute 1-5% of most comendite samples. Lithic types include hornfels, cogenetic volcanic rocks, porphyritic quartz syenite, and rarely cogenetic plutonic r ocks. The trachyte consists of phenocrysts (2-3 mm) of pink alkali feldspar set in a dense (<0.1 mm) groundmass of alkali feldspar. Accessories include abundant hematite and minor zircon, magnetite, epidote and clinozoisite. The breccias contains an gular to subrounded rocks ranging from a few centimeters to a meter in size. Lithic fragments include a variety of metamorphic rock lithologies, Paleozoic intrusive rocks, and cogenetic volcanic and hypabyssal rocks.