Winthrop H.S.

DETAILED SYLLABUS FOR
HONORS CHEMISTRY

(SUBJECT TO CHANGE)
•   Eli C. Minkoff, Ph.D.   •
Revised December, 2010
 

A comprehensive first-year chemistry course for all students interested in any science.
Chemistry is fundamental to the understanding of all other sciences. The intellectual and practical
skills learned in this course are transferable to all other science fields and many nonsciences.
Please note that this syllabus remains subject to change.
_________________________

EXPECTATIONS:

TEXT:     Davis, Metcalfe, Williams, and Castka   MODERN CHEMISTRY (2002 copyright or 2005 printing) (Holt Rinehart Winston).

  UNIT 0. MEASUREMENTS AND CALCULATIONS     (Chapter 2)
    (Massachusetts Curriculum Frameworks, standard III)
  • Overview of course; course procedures; safety contracts
  • What is chemistry? What is matter?
  • Scientific notation
  • SI measurements
  • Accuracy; uncertainty and precision
  • Significant figures
  • Dimensional analysis; unit conversions
  • Temperature
  • Density
  UNIT 1. INTRODUCTION: MATTER AND ITS CHANGES     (Chapter 1)
    (Massachusetts Curriculum Frameworks, content standard 1)
  • SCIENTIFIC STUDY OF MATTER, ITS PROPERTIES, AND ITS CHANGES
  • Scientific method
  • Matter;   states of matter
  • Elements, compounds, mixtures
  • Chemical & physical properties
  • Chemical & physical changes
  • Separating mixtures
  • REVIEW

  UNIT 2. THE ATOM AND ATOMIC STRUCTURE     (Chapters 3-4)
    (Massachusetts Curriculum Frameworks, most of content standard 2; remainder in unit 9)
  • Elements
  • Dalton's atomic theory
  • Atomic structure; Rutherford's gold foil experiment
  • Protons, neutrons, electrons
  • Atomic numbers, masses, isotopes
  • Rutherford's atom (planetary model)
  • Octet rule and ion formation
  • Introducing the Periodic Table.
  • (SIMPLE IONIC COMPOUNDS will be introduced here, from ch. 7)
  • Atomic spectra; quantum levels
  • Wave mechanics and electron orbitals
  • Bohr's quantum model of the atom
  • Electron orbitals and their shapes
  • Aufbau principle, orbitals, and the periodic table
  • REVIEW

Target date: end of September



  UNIT 3. PERIODICITY AND THE PERIODIC TABLE     (Chapter 5)
    (Massachusetts Curriculum Frameworks, content standard 3)
  • DESCRIPTIVE CHEMISTRY of some elements (see the "Elements Handbook"
    in the back of the text.)
  • Periodic relations; Mendeleev
  • Atomic properties and periodic trends


  UNIT 4. CHEMICAL BONDING AND COMPOUNDS     (Chapters 6-7)
    (Massachusetts Curriculum Frameworks, content standard 4)
  • Types of bonds;   molecular compounds
  • Electronegativity
  • Bond polarity; dipoles
  • Ions and ionic bonds
  • Ionic compounds and their formulas
  • Naming ionic compounds
  • Compounds containing polyatomic ions
  • Special naming rules for acids

    Target: End of 1st marking period

  • Covalent bonding
  • Covalent compounds and their names
  • Valence electrons and Lewis structures
  • VSEPR theory and molecular geometry
  • Writing formulas from names
  • Molecular weights
  • The mole; Avogadro's hypothesis or law
  • Molarity
  • Percentage composition problems
  • Determining formulas from percent composition
  • REVIEW
  • EXAM COVERING UNITS 0-4

Target: Thanksgiving break



  UNIT 5. CHEMICAL REACTIONS AND QUANTITIES     (Chapters 8-9)
    (Massachusetts Curriculum Frameworks, content standard 5)
  • Chemical reactions;   evidence of a reaction
  • Writing and balancing chemical equations
  • Types of reactions: synthesis; decomposition; single replacement; double replacement
  • Predicting various reactions: precipitations, acid/base reactions, oxidation/reduction reactions, etc.
  • Molecular weights
  • Moles and Avogadro's law
  • Stoichiometry
  • Limiting reactants
  • Percentage yield
  • REVIEW

Target: End of 2nd marking period



  UNIT 6. STATES OF MATTER:   SOLIDS, LIQUIDS, GASES     (Chapters 10-12 and 17)
    (Massachusetts Curriculum Frameworks, content standard 6)
  • GASES AND GAS LAWS (Ch. 10-12):
  • Importance of gases in chemistry; Lavoisier
  • Pressure and Torricelli
  • Gas laws: Boyle's, Charles's, combined; absolute temperatures
  • DESCRIPTIVE CHEMISTRY of some gases (see the "Elements Handbook"
    in the back of the text)
  • Combining volumes
  • Gram-Molecular Volume; Avogadro revisited
  • Ideal gas law: PV=nRT
  • Dalton's law of partial pressures
  • Gases and balancing equations
  • Gas stoichiometry
  • Kinetic molecular theory
  • Effusion and diffusion

    Target: end of February

  • LIQUIDS, SOLIDS, AND PHASE CHANGES (Ch. 12)
  • Water and its phase changes
  • Phase changes in general
  • Intermolecular forces, especially in liquids
  • Evaporation and vapor pressure
  • Metallic and nonmetallic solids
  • Bonding in solids
  • DESCRIPTIVE CHEMISTRY: Solid and liquid elements
  • REACTION ENERGY (THERMOCHEMISTRY) (Ch. 17)
  • Energy; heat and temperature
  • Thermodynamics; heat exchange and calorimetry
  • Enthalpy of a reaction
  • Exothermic and endothermic processes
  • Thermochemistry; Hess's law
  • Entropy and randomness
  • Free energy, spontaneity, and the "driving force" in chemical reactions
  • The Gibbs equation
  • Relation of spontaneity to equilibrium
  • Practical considerations; energy sources
  • REVIEW
  • CUMULATIVE EXAM THROUGH UNIT 6

    Target date: End of 3rd marking period



  UNIT 7. SOLUTIONS, RATES, AND EQUILIBRIA     (Chapters 13-14 and 18)
    (Massachusetts Curriculum Frameworks, content standard 7)
  • SOLUTION CHEMISTRY
  • Solutions and solubility
  • Concentration; dilutions
  • Stoichiometry with solutions
  • Colligative properties
  • KINETICS
  • Kinetics; reaction rates
  • Collision theory
  • Activation energy and catalysts
  • Finding rate laws
  • EQUILIBRIUM CHEMISTRY
  • One-phase equilibria
  • Heterogeneous equilibria
  • LeChâtelier's principle
  • Applications
  • REVIEW

    Target: end of April



  UNIT 8. ACIDS, BASES, AND ELECTRON TRANSFER     (Chapters 15-16 and 19)
    (Massachusetts Curriculum Frameworks, content standard 8)
  • ACIDS AND BASES
  • Acids and bases: Arrhenius; Brønsted/Lowry
  • Neutralization; titration; normality
  • Strong and weak acids and bases
  • Water as an acid and a base
  • pH scale
  • Buffers; acid-base equilibria
  • REVIEW
  • ELECTRON TRANSFER REACTIONS:   OXIDATION AND REDUCTION
  • Oxidation states
  • Oxidation and reduction reactions
  • Balancing redox reactions (half-reaction method)
  • Electrochemistry: Galvanic cells, batteries, etc.
  • Electrolysis
  • REVIEW
  • CUMULATIVE EXAM THROUGH UNIT 8

Target: Memorial Day



  UNIT 9. NUCLEAR CHEMISTRY     (Chapter 22)
    (Massachusetts Curriculum Frameworks, remainder of content standard 2 not already covered in unit 2)
  • Radioactivity
  • Transformations
  • Decay, half-life, dating; reaction series
  • Medical and other applications
  • Nuclear energy
  • Effects of radiation
  • REVIEW



  UNIT 10. INTRODUCTION TO ORGANIC CHEMISTRY     (Chapters 20-21)
  • Importance of carbon
  • Hydrocarbons: alkanes
  • Isomers
  • IUPAC names
  • Petroleum chemistry
  • Alkenes, alkynes
  • Aromatic hydrocarbons
  • Functional groups
  • Alcohols, etc.
  • Other functional groups
  • Organic acids & esters; amines
  • Polymers
  • Biological chemistry
  • REVIEW
  • FINAL EXAM

Target: End of year





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